Hi Manju,
Check the field 0VALSTCKQTY Quantity of valuated stock, for this KF --> if you check the "Aggregation" Tab, Non-Cumulative properties you will find the below 2 KFs as Inflow and Out flow.
Inflow: 0RECVALSTCK Quantity Received into Valuated Stock
Outflow: 0ISSVALSTCK Quantity Issued from Valuated Stock
0VALSTCQTY = 0RECVALSTCK - 0ISSVALSTCK
Now compare the values in ECC using the above KF : 0VALSTCQTY.
Regards
KP